Araçatuba, Brazil

This city of 159,557 people in Brazil's São Paulo state may not be the first place that comes to mind for an expat, and with good reason. The tertiary sector dominates Araçatuba's economy, accounting for nearly 80% of its GDP, while industry is just under 19%. So don't expect a booming job market or wealth of opportunities. Motorcycles and scooters make up a staggering 37% of vehicles, much higher than the national average - a sign of the city's transportation challenges.

That said, Araçatuba has its charms. As a university hub in northwest São Paulo, it offers an academic atmosphere. The annual Expô Araçatuba agricultural fair is a major draw. But persistent bureaucracy and a lack of glamour mean this city is best suited for those seeking a quieter, more provincial Brazilian experience, rather than high-flying expats.