São Carlos, Brazil

Capital City

With a population of just 158,221, São Carlos is a far cry from the bustling metropolises of Brazil. The city's economy revolves around industry and agriculture, with the tertiary sector making up a healthy 65.9% of GDP. However, bureaucracy is a persistent headache, with the municipality home to over two dozen contaminated sites, primarily from fuel stations and illegal dumps. While São Carlos boasts a high ratio of PhDs per capita and a robust university presence, the city's hot, windy climate and irregular urban planning make it best suited for those seeking a quieter, more provincial lifestyle away from the crowds.