Xangongo, Angola

With a population of just 35,000, Xangongo is a sleepy outpost that offers little beyond basic infrastructure. The town was once a battleground during Angola's civil war, and its bridge over the Cunene River was destroyed by South African forces. Today, the area remains a persistent headache for bureaucracy and red tape.

For those seeking an off-the-beaten-path experience in Angola, Xangongo may hold some appeal. But the lack of amenities and lingering security concerns make it a tough sell for most expats looking to start a new life abroad.