Jaboticabal, Brazil

With just 59,133 residents, Jaboticabal is a small-town Brazilian outpost that lacks the charms of Rio or the dynamism of São Paulo. While its agriculture-focused economy may appeal to some, the bureaucracy around telecommunications is a persistent headache for locals and expats alike. And with the city responsible for a mere 8.5% of São Paulo state's GDP, the career opportunities here are limited.

Overall, Jaboticabal seems best suited for those seeking a quiet, provincial lifestyle, rather than ambitious professionals seeking the next big thing. The lure of cheap real estate and a slower pace of life may outweigh the lack of modern amenities for some, but this is hardly Brazil's most enticing destination.