Amambai, Brazil

With a population of just 25,951, Amambai is a sleepy outpost in Brazil's Mato Grosso do Sul state. The town's remote, rural setting and vast 4,202 square kilometer area make it feel worlds away from the urban bustle of Brazil's megacities. However, that isolation comes with a price - bureaucracy is a persistent headache for residents.

While the city can boast one notable citizen, singer-songwriter Ana Castela, there's little else to recommend Amambai as a destination. The lack of infrastructure and services typical of small Brazilian towns is likely to frustrate many expats or young professionals. This place is best suited for those seeking a simple, quiet life far from the crowds.